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Introducing UOP’s CLR-204 Adsorbent

Breakthrough HCl removal adsorbent provides extended life and limited reactivity

UOP has developed a revolutionary chloride removal adsorbent, which maximizes chloride capacity while minimizing hydrocarbon reactivity. CLR-204 adsorbent was designed using innovative materials and manufacturing methods, which have been shown to significantly increase performance. CLR-204 adsorbent is particularly well-suited for treating CCR Platforming unit net gas and Oleflex unit effluent streams. It has also been shown to function in a variety of other HCl removal applications.

The presence of HCl is a common issue for refiners, who often inject chloride-containing compounds to maintain performance of precious metal catalysts. This practice results in an unavoidable presence of HCl in the product streams, which can give rise to problems such as corrosion, salt accumulation, or early deactivation of downstream catalysts and adsorbents.

Refiners typically remove HCl using supported sodium or alkaline earth metal adsorbents. Many of these products are limited by low chloride capacity, which necessitates frequent unloading and disposal. Other products react with hydrocarbon streams, forming unwanted oligomers known as green oil, or organic chlorides. As chloride loading of these adsorbents increases, certain products can become highly reactive. The problems created by these by-products can range from a mild nuisance to a serious operational hazard.

CLR-204 adsorbent improves upon existing technology by extending the useful life and by minimizing reactivity. The unique structure of CLR-204 adsorbent allows the adsorbent to operate under difficult process conditions, combined gas and liquid phase flow. CLR-204 adsorbent was successfully commercialized in 2006 with resoundingly positive feedback. CLR-204 adsorbent provides customers with breakthrough performance at a competitive price, setting a new standard for HCl removal products.

For more information on CLR-204 adsorbent, contact your local sales office or contact us directly using our information request form.

For more detailed information on the Platforming or Oleflex processes, click on the following links:
Platforming Process
Oleflex Process